Search results for "quantum [effect]"
showing 10 items of 5105 documents
Thermochemical properties of small open-shell systems: experimental and high-levelab initioresults for NH2and
2006
The first adiabatic ionization energy and the first singlet–triplet splitting of the amidogen radical (NH2) have been determined by high-level ab initio quantum chemistry based on the coupled-cluster approach (90 041 and 10 319 cm−1, respectively) and by high-resolution pulsed-field-ionization zero-kinetic-energy (PFI-ZEKE) photoelectron spectroscopy (90 083.8 ± 1.0 and 10 222.0 ± 1.3 cm−1, respectively). A comparison between the theoretical and experimental values demonstrates the predictive powers of high-level ab initio theory in the derivation of the thermochemical properties of small molecular systems. The absolute accuracy of better than 100 cm−1 alleviates the experimental search for…
High-efficiency silicon-compatible photodetectors based on Ge quantum dots
2011
We report on high responsivity, broadband metal/insulator/semiconductor photodetectors with amorphous Ge quantum dots (a-Ge QDs) as the active absorbers embedded in a silicon dioxide matrix. Spectral responsivities between 1-4 A/W are achieved in the 500-900 nm wavelength range with internal quantum efficiencies (IQEs) as high as ∼700%. We investigate the role of a-Ge QDs in the photocurrent generation and explain the high IQE as a result of transport mechanisms via photoexcited QDs. These results suggest that a-Ge QDs are promising for high-performance integrated optoelectronic devices that are fully compatible with silicon technology in terms of fabrication and thermal budget. © 2011 Amer…
Influence of the electro-optical properties of an a-Si:H single layer on the performances of a pin solar cell
2012
We analyze the results of an extensive characterization study involving electrical and optical measurements carried out on hydrogenated amorphous silicon (α-Si:H) thin film materials fabricated under a wide range of deposition conditions. By adjusting the synthesis parameters, we evidenced how conductivity, activation energy, electrical transport and optical absorption of an α-Si:H layer can be modified and optimized. We analyzed the activation energy and the pre-exponential factor of the dark conductivity by varying the dopant-to-silane gas flow ratio. Optical measurements allowed to extract the absorption spectra and the optical bandgap. Additionally, we report on the temperature dependen…
Optical gain, spontaneous and stimulated emission of surface plasmon polaritons in confined plasmonic waveguide
2010
International audience; We develop a theoretical model to compute the local density of states in a confined plasmonic waveguide. Based on this model, we derive a simple formula with a clear physical interpretation for the lifetime modification of emitters embedded in the waveguide. The gain distribution within the active medium is then computed following the formalism developed in a recent work [Phys. Rev. B 78, 161401 (2008)], by taking rigorously into account the pump irradiance and emitters lifetime modifications in the system. We finally apply this formalism to describe gain–assisted propagation in a dielectric–loaded surface plasmon polariton waveguide.
TASCAを用いたCn, Nh, Fl化学実験のためのHg, Tl, PbのSiO2及びAu表面に対するオンライン化学吸着研究
2018
Online gas-solid adsorption studies with single atom quantities of Hg, Tl, and Pb on SiO$_{2}$ and Au surfaces were carried out using short-lived radioisotopes with half-lives in the range of 4-49 s. This is a model study to measure adsorption enthalpies of superheavy elements Cn, Nh, and Fl. The short-lived isotopes were produced and separated by the gas-filled recoil separator TASCA at GSI. The products were stopped in He gas, and flushed into gas chromatography columns made of Si detectors whose surfaces were covered by SiO$_{2}$ or Au. The short-lived Tl and Pb were successfully measured by the Si detectors with the SiO$_{2}$ surface at room temperature. On the other hand, the Hg did no…
Dynamics of thick discs around Schwarzschild-de Sitter black holes
2003
We consider the effects of a cosmological constant on the dynamics of constant angular momentum discs orbiting Schwarzschild-de Sitter black holes. The motivation behind this study is to investigate whether the presence of a radial force contrasting the black hole's gravitational attraction can influence the occurrence of the runaway instability, a robust feature of the dynamics of constant angular momentum tori in Schwarzschild and Kerr spacetimes. In addition to the inner cusp near the black hole horizon through which matter can accrete onto the black hole, in fact, a positive cosmological constant introduces also an outer cusp through which matter can leave the torus without accreting on…
Relativistic simulations of rotational core collapse : I. Methods, initial models, and code tests
2002
We describe an axisymmetric general relativistic code for rotational core collapse. The code evolves the coupled system of metric and fluid equations using the ADM 3+1 formalism and a conformally flat metric approximation of the Einstein equations. The relativistic hydrodynamics equations are formulated as a first-order flux-conservative hyperbolic system and are integrated using high-resolution shock-capturing schemes based on Riemann solvers. We assess the quality of the conformally flat metric approximation for relativistic core collapse and present a comprehensive set of tests which the code successfully passed. The tests include relativistic shock tubes, the preservation of the rotatio…
Probing mechanical quantum coherence with an ultracold-atom meter
2011
We propose a scheme to probe quantum coherence in the state of a nano-cantilever based on its magnetic coupling (mediated by a magnetic tip) with a spinor Bose Einstein condensate (BEC). By mapping the BEC into a rotor, its coupling with the cantilever results in a gyroscopic motion whose properties depend on the state of the cantilever: the dynamics of one of the components of the rotor angular momentum turns out to be strictly related to the presence of quantum coherence in the state of the cantilever. We also suggest a detection scheme relying on Faraday rotation, which produces only a very small back-action on the BEC and it is thus suitable for a continuous detection of the cantilever'…
Ab initio quasi-relativistic calculations on angular momentum and magnetic couplings of molecular electronic states.
2002
Abstract We formulate an ab initio method of quasirelativistic calculations on angular momentum and magnetic transition matrix elements between adiabatic electronic states of molecules. Our approach is based on the construction of a state-selective effective Hamiltonian and transition density matrices by means of the multireference many-body perturbation theory. Pilot applications to the evaluation of B 0 + u → B ″1 u predissociation matrix elements in I 2 and interactions in the B 0 + u ∼ B 1 u complex of Te 2 are reported.
Quantum state engineering using one-dimensional discrete-time quantum walks
2017
Quantum state preparation in high-dimensional systems is an essential requirement for many quantum-technology applications. The engineering of an arbitrary quantum state is, however, typically strongly dependent on the experimental platform chosen for implementation, and a general framework is still missing. Here we show that coined quantum walks on a line, which represent a framework general enough to encompass a variety of different platforms, can be used for quantum state engineering of arbitrary superpositions of the walker's sites. We achieve this goal by identifying a set of conditions that fully characterize the reachable states in the space comprising walker and coin, and providing …